No. IPv6 deployment is tricky (though accelerating), but not all that scary, because it's easy to run IPv4 and IPv6 alongside each other; virtually everybody running IPv6 does that.
The problem with DNSSEC is that deploying it breaks DNS. Anything that goes wrong with your DNSSEC configuration is going to knock your whole site off the Internet for a large fraction of Internet users.
Very aware that dual stack deployment is a thing. It's really the only sane way to do the migration for any sizable network, but obviously increases complexity vs a hopeful future of IPv6 only.
Good point about dnssec, but this is par for the course with good security technologies - it could break things used to be an excuse for supporting plaintext http as a fallback from https / TLS. If course having an insecure fallback means downgrade attacks are possible and often easy, so defeats a lot of the purpose of the newer protocols
I don't think the failure modes for DNSSEC really are par for the course for security technologies, just for what it's worth; I think DNSSEC's are distinctively awful. HPKP had similar problems, and they killed HPKP.
The problem with DNSSEC is that deploying it breaks DNS. Anything that goes wrong with your DNSSEC configuration is going to knock your whole site off the Internet for a large fraction of Internet users.