Because time zones span ~15 degrees of longitude, and the sunset can be up to one hour difference between each side of the time zone. Also, I move north and south during my travels, which also changes sunset, and is not reflected in the time zone.
My main gripe is that it only has a single color temp setting. I use three with f.lux and it makes a huge difference. 5800K during the day, 3400K in the evening (between sunset and 11pm) and 1900K after 11pm, until an hour after sunrise.
My phone is jarring in the evening because it's way cooler than my display.
I want candlelight. I replaced a bunch of bulbs in my house so that before I go to bed I have no light sources warmer than a candle, other than my phone.